Manufacture of ASTM A351, ASME SA351 Stainless Steel, Duplex, Super Duplex Castings

Manufacture of ASTM A351, ASME SA351 Stainless Steel, Duplex, Super Duplex Castings

Manufacturer of ASTM A-351, ASME SA-351 Stainless Steel, Duplex, Super Duplex Casting
Designation: A 351/A 351M – 03
Standard Specification for
Castings, Austenitic, Austenitic-Ferritic (Duplex), for
Pressure-Containing Parts1
This standard is issued under the fixed designation A 351/A 351M; the number immediately following the designation indicates the year
of original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval.
A superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.

  1. Scope*
    1.1 This specification2 covers austenitic and austeniticferritic
    (duplex) steel castings for valves, flanges, fittings, and
    other pressure-containing parts (Note 1).
    NOTE 1—Carbon steel castings for pressure-containing parts are covered
    by Specification A 216/A 216M, and low-alloy steel castings by
    Specification A 217/A 217M.
    1.2 A number of grades of austenitic and austenitic-ferritic
    steel castings are included in this specification. Since these
    grades possess varying degrees of suitability for service at high
    temperatures or in corrosive environments, it is the responsibility
    of the purchaser to determine which grade shall be
    furnished. Selection will depend on design and service conditions,
    mechanical properties, and high-temperature or
    corrosion-resistant characteristics, or both.
    1.2.1 Because of thermal instability, Grades CE20N, CF3A,
    CF3MA, and CF8A are not recommended for service at
    temperatures above 800°F [425°C].
    1.2.2 Because of embrittlement phases, Grade CD4MCu is
    not recommended for service at temperatures above 600°F
    [316°C].
    1.3 The values stated in either inch-pound units or SI units
    are to be regarded separately as standard. Within the text, the
    SI units are shown in brackets. The values stated in each
    system are not exact equivalents; therefore, each system must
    be used independently of the other. Combining values from the
    two systems may result in nonconformance with the specification.
  2. Referenced Documents
    2.1 ASTM Standards:
    A 216/A 216M Specification for Steel Castings, Carbon,
    Suitable for Fusion Welding, for High-Temperature Service3
    A 217/A 217M Specification for Steel Castings, Martensitic
    Stainless and Alloy, for Pressure-Containing Parts,
    Suitable for High-Temperature Service3
    A 488/A 488M Practice for Steel Castings,Welding, Qualification
    of Procedures and Personnel3
    A 703/A 703M Specification for Steel Castings, General
    Requirements, for Pressure-Containing Parts3
    E 165 Test Method for Liquid Penetrant Examination4
    E 709 Guide for Magnetic Particle Examination4
    2.2 Manufacturers Standardization Society of the Valve and
    Fittings Industry Standard:
    SP-55 Quality Standard for Steel Castings for Valves,
    Flanges, and Fittings and Other Components (Visual
    Method)5
  3. General Conditions for Delivery
    3.1 Material furnished to this specification shall conform to
    the requirements of Specification A 703/A 703M, including
    any supplementary requirements that are indicated in the
    purchase order. Failure to comply with the general requirements
    of Specification A 703/A 703M constitutes nonconformance
    with this specification. In case of conflict between the
    requirements of this specification and Specification A 703/
    A 703M, this specification shall prevail.
    3.2 The post weld heat treatment requirements of Supplementary
    Requirement S11 may be specified when austenitic
    castings other than HK, HT, or CT15C are to be subjected to
    severe corrosive service.
    1 This specification is under the jurisdiction of ASTM Committee A01 on Steel,
    Stainless Steel, and Related Alloys and is the direct responsibility of Subcommittee
    A01.18 on Castings.
    Current edition approved May 10, 2003. Published June 2003. Originally
    approved in 1952. Last previous edition approved in 2000 as A 351/A 351M – 00.
    2 For ASME Boiler and Pressure Vessel Code applications, see related Specification
    SA-351/SA-351M in Section II of that code.
    3 Annual Book of ASTM Standards, Vol 01.02.
    4 Annual Book of ASTM Standards, Vol 03.03.
    5 Available from Manufacturers’ Standardization Society of the Valve and
    Fittings Industry, 1815 N. Fort Myer Drive, Arlington, VA 22209.
    1
    *A Summary of Changes section appears at the end of this standard.
    Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA Qingdao Casting Quality Industrial Co., Limited 19428-2959, United States. http://www.castingquality.com
  4. Ordering Information
    4.1 The inquiry and order should include or indicate the
    following:
    4.1.1 A description of the casting by pattern number or
    drawing (dimensional tolerances shall be included on the
    casting drawing),
    4.1.2 Grade of steel,
    4.1.3 Options in the specification, and
    4.1.4 Supplementary requirements desired, including the
    standards of acceptance.
  5. Process
    5.1 The steel shall be made by the electric furnace process
    with or without separate refining such as argon-oxygen decarburization
    (AOD).
  6. Heat Treatment
    6.1 All castings shall receive a heat treatment at the temperature
    specified in Table 1, followed by a quench in water or
    rapid cool by other means except as noted.
    NOTE 2—Proper heat treatment of these alloys is usually necessary to
    enhance corrosion resistance and in some cases to meet mechanical
    properties. Minimum heat-treat temperatures are specified; however, it is
    sometimes necessary to heat-treat at higher temperatures, hold for some
    minimum time at temperature and then rapidly cool the castings in order
    to enhance the corrosion resistance and meet mechanical properties.
  7. Chemical Composition
    7.1 The steel shall conform to the requirements as to
    chemical composition prescribed in Table 2.
  8. Tensile Properties
    8.1 Steel used for the castings shall conform to the requirements
    as to tensile properties prescribed in Table 3.
  9. Quality
    9.1 The surface of the casting shall be examined visually
    and shall be free of adhering sand, scale, cracks, and hot tears.
    Other surface discontinuities shall meet the visual acceptance
    standards specified in the order. Visual Method SP 55 or other
    visual standards may be used to define acceptable surface
    discontinuities and finish. Unacceptable visual surface discontinuities
    shall be removed and their removal verified by visual
    examination of the resultant cavities.
    9.2 When additional inspection is desired, Supplementary
    Requirements S5, S6, and S10 may be ordered.
    9.3 The castings shall not be peened, plugged, or impregnated
    to stop leaks.
  10. Repair by Welding
    10.1 Repairs shall be made using procedures and welders
    qualified under Practice A 488/A 488M.
    10.2 Weld repairs shall be inspected to the same quality
    standards that are used to inspect the castings. When castings
    are produced with Supplementary Requirement S5 specified,
    weld repairs on castings that have leaked on hydrostatic test, or
    on castings in which the depth of any cavity prepared for repair
    welding exceeds 20 % of the wall thickness or 1 in. [25 mm],
    whichever is smaller, or on castings in which any cavity
    prepared for welding is greater than approximately 10 in.2[65
    cm2], shall be radiographed to the same standards that are used
    to inspect the castings. When castings are produced with
    Supplementary Requirement S6 specified, weld repairs shall be
    inspected by liquid penetrant examination to the same standards
    that are used to inspect the castings.
    NOTE 3—When austenitic steel castings are to be used in services
    where they will be subject to stress corrosion, the purchaser should so
    indicate in his order and such castings should be solution-heat treated
    following all weld repairs.
  11. Keywords
    11.1 austenitic stainless steel; duplex stainless steel; pressure
    containing parts; stainless steel; steel castings
    TABLE 1 Heat-Treatment Requirements
    Grade
    Temperature, min
    °F °C
    HK30, HK40, HT30, CT15C as-cast as-cast
    CF3, CF3A, CF8, CF8A, CF3M,
    CF3MA, CF8M, CF3MN, CG3M, CF10,
    CF10M, CG8M, CD4MCu
    1900 1040
    CF10SMnN, CF8C, CF10MC 1950 1065
    CD3MWCuN 2010 1100
    CN7M, CG6MMN, CE8MN 2050 1120
    CK3MCuN, CN3MN, CH8, CH10, CH20,
    CK20
    2100 1150
    CE20NA 2225 1220
    A Grade shall be quenched in water or the castings may be furnace cooled to
    2050°F [1120°C] minimum, held for 15 min minimum and then quenched in water
    or rapidly cooled by other means.
    A 351/A 351M – 03
    2
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    TABLE 2 Chemical Requirements
    NOTE—Tungsten is a new element for Table 2.
    Element, %
    (max, except
    where
    range is
    given)
    CF3,
    CF3A
    J92700
    CF8,
    CF8A
    J92600
    CF3M,
    CF3MA
    J92800
    CF8M
    J92900
    CF3MN
    J92804
    CF8C
    J92710
    CF10
    J92950
    CF10M
    J92901
    CH8
    J93400
    CH10
    J93401
    CH20
    J93402
    CK20
    J94202
    HK30
    J94203
    HK40
    J94204
    Carbon 0.03 0.08 0.03 0.08 0.03 0.08 0.04– 0.04– 0.08 0.04– 0.04– 0.04– 0.25– 0.35–
    0.10 0.10 0.10 0.20 0.20 0.35 0.45
    Manganese 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50
    Silicon 2.00 2.00 1.50 1.50 1.50 2.00 2.00 1.50 1.50 2.00 2.00 1.75 1.75 1.75
    Sulfur 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.040
    Phosphorus 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.040
    Chromium 17.0– 18.0– 17.0– 18.0– 17.0– 18.0– 18.0– 18.0– 22.0– 22.0– 22.0– 23.0– 23.0– 23.0–
    21.0 21.0 21.0 21.0 21.0 21.0 21.0 21.0 26.0 26.0 26.0 27.0 27.0 27.0
    Nickel 8.0–
    12.0
    8.0–
    11.0
    9.0–
    13.0
    9.0–
    12.0
    9.0–
    13.0
    9.0–
    12.0
    8.0–
    11.0
    9.0–
    12.0
    12.0–
    15.0
    12.0–
    15.0
    12.0–
    15.0
    19.0–
    22.0
    19.0–
    22.0
    19.0–
    22.0
    Molybde- 0.50 0.50 2.0– 2.0– 2.0– 0.50 0.50 2.0– 0.50 0.50 0.50 0.50 0.50 0.50
    num 3.0 3.0 3.0 3.0
    Columbium . . . . . . . . . . . . . . . A . . . . . . . . . . . . . . . . . . . . . . . .
    (niobium)
    Vanadium . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
    Nitrogen . . . . . . . . . . . . 0.10– . . . . . . . . . . . . . . . . . . . . . . . . . . .
    0.20
    Copper . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
    Tungsten . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
    Iron . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
    Element, %
    (max, except
    where
    range is
    given)
    HT30
    N08030
    CF10MC
    CN7M
    N08007
    CN3MN
    J94651
    CD-
    4MCu
    J93370
    CE8MN
    CG-
    6MMN
    J93790
    CG8M
    J93000
    CF10SMnN
    J92972
    CT15C
    N08151
    CK-
    3MCuN
    J93254
    CE20N
    J92802
    CG3M
    J92999
    CD3MWCuNB
    J93380
    Carbon 0.25– 0.10 0.07 0.03 0.04 0.08 0.06 0.08 0.10 0.05– 0.025 0.20 0.03 0.03
    0.35 max 0.15
    Manganese 2.00 1.50 1.50 2.00 1.00 1.00 4.00– 1.50 7.00– 0.15– 1.20 1.50 1.50 1.00
    max 6.00 9.00 1.50
    Silicon 2.50 1.50 1.50 1.00 1.00 1.50 1.00 1.50 3.50– 0.50– 1.00 1.50 1.50 1.00
    max 4.50 1.50
    Sulfur 0.040 0.040 0.040 0.010 0.04 0.040 0.030 0.04 0.030 0.03 0.010 0.040 0.04 0.025
    max
    Phosphorus 0.040 0.040 0.040 0.040 0.04 0.040 0.040 0.04 0.060 0.03 0.045 0.040 0.04 0.030
    max
    Chromium 13.0– 15.0– 19.0– 20.0– 24.5– 22.5– 20.50– 18.0– 16.0– 19.0– 19.5– 23.0– 18.0– 24.0–
    17.0 18.0 22.0 22.0 26.5 25.5 23.50 21.0 18.0 21.0 20.5 26.0 21.0 26.0
    Nickel 33.0–
    37.0
    13.0–
    16.0
    27.5–
    30.5
    23.5–
    25.5
    4.75–
    6.00
    8.0–
    11.0
    11.50–
    13.50
    9.0–
    13.0
    8.0–
    9.0
    31.0–
    34.0
    17.5–
    19.5
    8.0–
    11.0
    9.0–
    13.0
    6.5–
    8.5
    Molybde- 0.50 1.75– 2.0– 6.0– 1.75– 3.0– 1.50– 3.0– . . . . . . 6.0– 0.50 3.0– 3.0–
    num 2.25 3.0 7.0 2.25 4.5 3.00 4.0 7.0 4.0 4.0
    Columbium . . . C . . . . . . . . . . . . 0.10– . . . . . . 0.50– . . . . . . . . . . . .
    (niobium) 0.30 1.50
    Vanadium . . . . . . . . . . . . . . . . . . 0.10– . . . . . . . . . . . . . . . . . . . . .
    0.30
    Nitrogen . . . . . . . . . 0.18– . . . 0.10– 0.20– . . . 0.08– . . . 0.18– 0.08– . . . 0.20–
    0.26 0.30 0.40 0.18 0.24 0.20 0.30
    Copper . . . . . . 3.0–
    4.0
    0.75
    max
    2.75–
    3.25
    . . . . . . . . . . . . . . . 0.50–
    1.00
    . . . . . . 0.5–
    1.0
    Tungsten . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.5–
    1.0
    Iron . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Bal . . . . . .
    A Grade CF8C shall have a columbium content of not less than 8 times the carbon content but not over 1.00 %.
    B % Cr + 3.3 % Mo + 16 % N $ 40.
    C Grade CF10MC shall have a columbium content of not less than 10 times the carbon content but not over 1.20 %.
    A 351/A 351M – 03
    3
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    SUPPLEMENTARY REQUIREMENTS
    The following supplementary requirements shall not apply unless specified in the purchase order. A
    list of standardized supplementary requirements for use at the option of the purchaser is included in
    Specification A 703/A 703M. Those which are ordinarily considered suitable for use with this
    specification are given below. Others enumerated in Specification A 703/A 703M may be used with
    this specification upon agreement between the manufacturer and purchaser.
    S2. Destruction Tests
    S5. Radiographic Inspection
    S6. Liquid Penetrant Inspection
    S10. Examination of Weld Preparation
    S10.1 The method of performing the magnetic particle or
    liquid penetrant test shall be in accordance with Practice E 165
    or Practice E 709.
    S11. Post Weld Heat Treatment
    S11.1 All austenitic castings, except Grades HK, HT, and
    CT15C, which have been subjected to weld repairs, shall be
    given a post weld solution heat treatment.
    TABLE 3 Tensile Requirements
    CF3
    J92700
    CF3A
    J92700
    CF8
    J92600
    CF8A
    J92600
    CF3M
    J92800
    CF-
    3MA
    J92800
    CF8M
    J92900
    CF-
    3MN
    J92804
    CF8C
    J92710
    CF10
    J92950
    CF10M
    J92901
    CH8
    J93400
    CH10
    J93401
    CH20
    J93402
    CK20
    J94202
    HK30
    J94203
    HK40
    J94204
    Tensile strength, 70 77 70 77 70 80 70 75 70 70 70 65 70 70 65 65 62
    min, ksi [MPa] [485] [530] [485] [530] [485] [550] [485] [515] [485] [485] [485] [450] [485] [485] [450] [450] [425]
    Yield strength,A 30 35 30 35 30 37 30 37 30 30 30 28 30 30 28 35 35
    min, ksi [MPa] [205] [240] [205] [240] [205] [255] [205] [255] [205] [205] [205] [195] [205] [205] [195] [240] [240]
    Elongation in
    2 in. or
    50 mm,B
    min, %
    35.0 35.0 35.0 35.0 30.0 30.0 30.0 35.0 30.0 35.0 30.0 30.0 30.0 30.0 30.0 10.0 10.0
    Reduction of
    area, min,%
    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
    HT30
    N08030
    CF-
    10MC
    CN7M
    N08007
    CN-
    3MN
    J94651
    CD-
    4MCu
    J93370
    CE-
    8MN
    CG
    6MMN
    J93790
    CG8M
    J93000
    CF10SMnN
    J92972
    CT15C
    N08151
    CK-
    3MCuN
    J93254
    CE20N
    J92802
    CG3M
    J92999
    CD3MWCuN
    J93380
    Tensile strength, 65 70 62 80 100 95 85 75 85 63 80 80 75 100
    min, ksi [MPa] [450] [485] [425] [550] [690] [655] [585] [515] [585] [435] [550] [550] 515
    Yield strength,A 28 30 25 38 70 65 42.5 35 42.5 25 38 40 35 65
    min, ksi [MPa] [195] [205] [170] [260] [485] [450] [295] [240] [295] [170] [260] [275] 240
    Elongation in
    2 in. or
    50 mm,B
    min, %
    15.0 20.0 35.0 35 16.0 25.0 30.0 25.0 30.0 20.0 35 30.0 25 25.0
    Reduction of
    area, min,%
    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
    A Determine by the 0.2 % offset method.
    B When ICI test bars are used in tensile testing as provided for in Specification A 703/A 703M, the gage length to reduced section diameter ratio shall be 4 to 1.
    A 351/A 351M – 03
    4
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    SUMMARY OF CHANGES
    Committee A01 has identified the location of selected changes to this standard since the last issue (A 351/
    A 351M – 00) that may impact the use of this standard.
    (1) UNS numbers were added to Table 2 and Table 3.
    (www.astm.org).
    A 351/A 351M – 03

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