Manufacture of ASTM A333, ASME SA333 Carbon Steel, Alloy Steel Seamless, Welded Pipes

Manufacture of ASTM A333, ASME SA333 Carbon Steel, Alloy Steel Seamless, Welded Pipes

Manufacturer of ASTM A-333, ASME SA-333 Carbon Steel, Alloy Steel Seamless, Welded Pipe
Designation: A 333/A 333M – 04a
Standard Specification for
Seamless and Welded Steel Pipe for Low-Temperature
Service1
This standard is issued under the fixed designation A 333/A 333M; the number immediately following the designation indicates the year
of original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval.
A superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.

  1. Scope*
    1.1 This specification2 covers nominal (average) wall seamless
    and welded carbon and alloy steel pipe intended for use at
    low temperatures. Several grades of ferritic steel are included
    as listed in Table 1. Some product sizes may not be available
    under this specification because heavier wall thicknesses have
    an adverse affect on low-temperature impact properties.
    1.2 Supplementary Requirement S1 of an optional nature is
    provided. This shall apply only when specified by the purchaser.
    1.3 The values stated in either inch-pound units or SI units
    are to be regarded separately as standard. Within the text, the
    SI units are shown in brackets. The values stated in each
    system are not exact equivalents; therefore, each system must
    be used independently of the other. Combining values from the
    two systems may result in nonconformance with the specification.
    The inch-pound units shall apply unless the “M”
    designation of this specification is specified in the order.
    NOTE 1—The dimensionless designator NPS (nominal pipe size) has
    been substituted in this standard for such traditional terms as “nominal
    diameter,” “size,” and “nominal size.”
  2. Referenced Documents
    2.1 ASTM Standards: 3
    A 370 Test Methods and Definitions for Mechanical Testing
    of Steel Products
    A 999/A 999M Specification for General Requirements for
    Alloy and Stainless Steel Pipe
    A 671 Specification for Electric-Fusion-Welded Steel Pipe
    for Atmospheric and Lower Temperatures
    E 23 Test Methods for Notched Bar Impact Testing of
    Metallic Materials
  3. Ordering Information
    3.1 Orders for material under this specification should
    include the following, as required, to describe the material
    adequately:
    3.1.1 Quantity (feet, centimetres, or number of lengths),
    3.1.2 Name of material (seamless or welded pipe),
    3.1.3 Grade (Table 1),
    3.1.4 Size (NPS or outside diameter and schedule number of
    average wall thickness),
    3.1.5 Lengths (specific or random) (Section 9), (see the
    Permissible Variations in Length section of Specification
    A 999/A 999M),
    3.1.6 End finish (see the Ends section of Specification
    A 999/A 999M),
    3.1.7 Optional requirements, (see the Heat Analysis requirement
    in the Chemical Composition section of A 999/A 999M,
    the Repair by Welding section, and the section on Nondestructive
    Test Requirements),
    3.1.8 Test report required, (see the Certification section of
    Specification A 999/A 999M),
    3.1.9 Specification designation, and
    3.1.10 Special requirements or exceptions to this specification.
  4. Materials and Manufacture
    4.1 Manufacture—The pipe shall be made by the seamless
    or welding process with the addition of no filler metal in the
    welding operation. Grade 4 shall be made by the seamless
    process.
    NOTE 2—For electric-fusion-welded pipe, with filler metal added, see
    Specification A 671.
    4.2 Heat Treatment:
    4.2.1 All seamless and welded pipe, other than Grades 8 and
    11, shall be treated to control their microstructure in accordance
    with one of the following methods:
    1 This specification is under the jurisdiction of ASTM Committee A01 on Steel,
    Stainless Steel, and Related Alloys and is the direct responsibility of Subcommittee
    A01.10 on Stainless and Alloy Steel Tubular Products.
    Current edition approved May 1, 2004. Published June 2004. Originally
    approved in 1950. Last previous edition approved in 2004 as A 333/A 333M – 04.
    2 For ASME Boiler and Pressure Vessel Code applications see related Specification
    SA-333 in Section II of that Code.
    3 For referenced ASTM standards, visit the ASTM website, www.astm.org, or
    contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
    Standards volume information, refer to the standard’s Document Summary page on
    the ASTM website.
    1
    *A Summary of Changes section appears at the end of this standard.
    Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
    4.2.1.1 Normalize by heating to a uniform temperature of
    not less than 1500°F [815°C] and cool in air or in the cooling
    chamber of an atmosphere controlled furnace.
    4.2.1.2 Normalize as in 4.2.1.1, and, at the discretion of the
    manufacturer, reheat to a suitable tempering temperature.
    4.2.1.3 For the seamless process only, reheat and control hot
    working and the temperature of the hot-finishing operation to a
    finishing temperature range from 1550 to 1750°F [845 to
    945°C] and cool in air or in a controlled atmosphere furnace
    from an initial temperature of not less than 1550°F [845°C].
    4.2.1.4 Treat as in 4.2.1.3 and, at the discretion of the
    manufacturer, reheat to a suitable tempering temperature.
    4.2.1.5 Seamless pipe of Grades 1, 6, and 10 may be heat
    treated by heating to a uniform temperature of not less than
    1500°F [815°C], followed by quenching in liquid and reheating
    to a suitable tempering temperature, in place of any of the other
    heat treatments provided for in 4.2.1.
    4.2.2 Grade 8 pipe shall be heat treated by the manufacturer
    by either of the following methods:
    4.2.2.1 Quenched and Tempered—Heat to a uniform temperature
    of 1475 6 25°F [800 6 15°C]; hold at this temperature
    for a minimum time in the ratio of 1 h/in. [2 min/mm] of
    thickness, but in no case less than 15 min; quench by
    immersion in circulating water. Reheat until the pipe attains a
    uniform temperature within the range from 1050 to 1125°F
    [565 to 605°C]; hold at this temperature for a minimum time in
    the ratio of 1 h/in. [2 min/mm] of thickness, but in no case less
    than 15 min; cool in air or water quench at a rate no less than
    300°F [165°C]/h.
    4.2.2.2 Double Normalized and Tempered—Heat to a uniform
    temperature of 1650 6 25°F [900 6 15°C]; hold at this
    temperature for a minimum time in the ratio of 1 h/in. [2
    min/mm] of thickness, but in no case less than 15 min; cool in
    air. Reheat until the pipe attains a uniform temperature of 1450
    6 25°F [790 6 15°C]; hold at this temperature for a minimum
    time in the ratio of 1 h/in. [2 min/mm] of thickness, but in no
    case less than 15 min; cool in air. Reheat to a uniform
    temperature within the range from 1050 to 1125°F [565 to
    605°C]; hold at this temperature for a minimum time of 1 h/in.
    [2 min/mm] of thickness but in no case less than 15 min; cool
    in air or water quench at a rate not less than 300°F [165°C]/h.
    4.2.3 Whether to anneal Grade 11 pipe is per agreement
    between purchaser and supplier. When Grade 11 pipe is
    annealed, it shall be normalized in the range of 1400 to 1600°F
    [760 to 870°C].
    4.2.4 Material from which test specimens are obtained shall
    be in the same condition of heat treatment as the pipe
    furnished. Material from which specimens are to be taken shall
    be heat treated prior to preparation of the specimens.
    4.2.5 When specified in the order the test specimens shall be
    taken from full thickness test pieces which have been stress
    relieved after having been removed from the heat-treated pipe.
    The test pieces shall be gradually and uniformly heated to the
    prescribed temperature, held at that temperature for a period of
    time in accordance with Table 2, and then furnace cooled at a
    temperature not exceeding 600°F [315°C]. Grade 8 shall be
    cooled at a minimum rate of 300°F [165°C]/h in air or water to
    a temperature not exceeding 600°F [315°C].
  5. Chemical Composition
    5.1 The steel shall conform to the requirements as to
    chemical composition prescribed in Table 1.
    5.2 When Grades 1, 6, or 10 are ordered under this
    specification, supplying an alloy grade that specifically requires
    the addition of any element other than those listed for
    the ordered grade in Table 1 is not permitted. However, the
    addition of elements required for the deoxidation of the steel is
    permitted.
    TABLE 1 Chemical Requirements
    Element
    Composition, %
    Grade 1A Grade 3 Grade 4 Grade 6A Grade 7 Grade 8 Grade 9 Grade 10 Grade 11
    Carbon, max 0.30 0.19 0.12 0.30 0.19 0.13 0.20 0.20 0.10
    Manganese 0.40–1.06 0.31–0.64 0.50–1.05 0.29–1.06 0.90 max 0.90 max 0.40–1.06 1.15–1.50 0.60 max
    Phosphorus, max 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.035 0.025
    Sulfur, max 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.015 0.025
    Silicon … 0.18–0.37 0.08–0.37 0.10 min 0.13–0.32 0.13–0.32 … 0.10–0.35 0.35 max
    Nickel … 3.18–3.82 0.47–0.98 … 2.03–2.57 8.40–9.60 1.60–2.24 0.25 max 35.0–37.0
    Chromium … … 0.44–1.01 … … … … 0.15 max 0.50 max
    Copper … … 0.40–0.75 … … … 0.75–1.25 0.15 max …
    Aluminum … … 0.04–0.30 … … … … 0.06 max …
    Vanadium, max … … … … … … … 0.12 …
    Columbium, max … … … … … … … 0.05 …
    Molybdenum, max … … … … … … … 0.05 0.50 max
    Cobalt … … … … … … … … 0.50 max
    A For each reduction of 0.01 % carbon below 0.30 %, an increase of 0.05 % manganese above 1.06 % would be permitted to a maximum of 1.35 % manganese.
    TABLE 2 Stress Relieving of Test Pieces
    Metal TemperatureA,B Minimum Holding Time,
    h/in. [min/mm]
    Grades 1, 3, 6, 7, and 10 Grade 4C of Thickness
    °F °C °F °C
    1100 600 1150 620 1 [2.4]
    1050 565 1100 600 2 [4.7]
    1000 540 1050 565 3 [7.1]
    A For intermediate temperatures, the holding time shall be determined by
    straight-line interpolation.
    B Grade 8 shall be stress relieved at 1025 to 1085°F, [550 to 585°C], held for a
    minimum time of 2 h for thickness up to 1.0 in. [25.4 mm], plus a minimum of 1 h
    for each additional inch [25.4 mm] of thickness and cooled at a minimum rate of
    300°F [165°C]/h in air or water to a temperature not exceeding 600°F [315°C].
    C Unless otherwise specified, Grade 4 shall be stress relieved at 1150°F
    [620°C].
    A 333/A 333M – 04a
    2
  6. Product Analysis
    6.1 At the request of the purchaser, an analysis of one billet
    or two samples of flat-rolled stock from each heat or of two
    pipes from each lot shall be made by the manufacturer. A lot of
    pipe shall consist of the following:
    NPS Designator Length of Pipe in Lot
    Under 2 400 or fraction thereof
    2 to 6 200 or fraction thereof
    Over 6 100 or fraction thereof
    6.2 The results of these analyses shall be reported to the
    purchaser or the purchaser’s representative and shall conform
    to the requirements specified.
    6.3 If the analysis of one of the tests specified in 6.1 does
    not conform to the requirements specified, an analysis of each
    billet or pipe from the same heat or lot may be made, and all
    billets or pipe conforming to the requirements shall be accepted.
  7. Tensile Requirements
    7.1 The material shall conform to the requirements as to
    tensile properties prescribed in Table 3.
  8. Impact Requirements
    8.1 For Grades 1, 3, 4, 6, 7, 9, and 10, the notched-bar
    impact properties of each set of three impact specimens,
    including specimens for the welded joint in welded pipe with
    wall thicknesses of 0.120 in. [3 mm] and larger, when tested at
    temperatures in conformance with 14.1 shall be not less than
    the values prescribed in Table 4. The impact test is not required
    for Grade 11.
    8.1.1 If the impact value of one specimen is below the
    minimum value, or the impact values of two specimens are less
    than the minimum average value but not below the minimum
    value permitted on a single specimen, a retest shall be allowed.
    The retest shall consist of breaking three additional specimens
    and each specimen must equal or exceed the required average
    value. When an erratic result is caused by a defective specimen,
    or there is uncertainty in test procedures, a retest will be
    allowed.
    8.2 For Grade 8 each of the notched bar impact specimens
    shall display a lateral expansion opposite the notch of not less
    than 0.015 in. [0.38 mm].
    8.2.1 When the average lateral expansion value for the three
    impact specimens equals or exceeds 0.015 in. [0.38 mm] and
    the value for one specimen is below 0.015 in. [0.38 mm] but
    not below 0.010 in. [0.25 mm], a retest of three additional
    specimens may be made. The lateral expansion of each of the
    retest specimens must equal or exceed 0.015 in. [0.38 mm].
    8.2.2 Lateral expansion values shall be determined by the
    procedure in Test Methods and Definitions A 370.
    8.2.3 The values of absorbed energy in foot-pounds and the
    fracture appearance in percentage shear shall be recorded for
    information. A record of these values shall be retained for a
    period of at least 2 years.
  9. Lengths
    9.1 If definite lengths are not required, pipe may be ordered
    in single random lengths of 16 to 22 ft (Note 3) with 5 % 12 to
    16 ft (Note 3), or in double random lengths with a minimum
    average of 35 ft (Note 3) and a minimum length of 22 ft (Note
    3) with 5 % 16 to 22 ft (Note 3).
    NOTE 3—This value(s) applies when the inch-pound designation of this
    specification is the basis of purchase. When the “M” designation of this
    specification is the basis of purchase, the corresponding metric value(s)
    shall be agreed upon between the manufacturer and purchaser.
  10. Workmanship, Finish and Appearance
    10.1 The pipe manufacturer shall explore a sufficient number
    of visual surface imperfections to provide reasonable
    assurance that they have been properly evaluated with respect
    to depth. Exploration of all surface imperfections is not
    required but may be necessary to ensure compliance with 10.2.
    10.2 Surface imperfections that penetrate more than 12½ %
    of the nominal wall thickness or encroach on the minimum
    wall thickness shall be considered defects. Pipe with such
    defects shall be given one of the following dispositions:
    10.2.1 The defect may be removed by grinding provided
    that the remaining wall thickness is within specified limits.
    10.2.2 Repaired in accordance with the repair welding
    provisions of 10.5.
    10.2.3 The section of pipe containing the defect may be cut
    off within the limits of requirements on length.
    10.2.4 The defective pipe may be rejected.
    10.3 To provide a workmanlike finish and basis for evaluating
    conformance with 10.2, the pipe manufacturer shall
    remove by grinding the following:
    10.3.1 Mechanical marks, abrasions and pits, any of which
    imperfections are deeper than 1⁄16 in. [1.6 mm], and
    10.3.2 Visual imperfections commonly referred to as scabs,
    seams, laps, tears, or slivers found by exploration in accordance
    with 10.1 to be deeper than 5 % of the nominal wall
    thickness.
    10.4 At the purchaser’s discretion, pipe shall be subject to
    rejection if surface imperfections acceptable under 10.2 are not
    scattered, but appear over a large area in excess of what is
    considered a workmanlike finish. Disposition of such pipe shall
    be a matter of agreement between the manufacturer and the
    purchaser.
    10.5 When imperfections or defects are removed by grinding,
    a smooth curved surface shall be maintained, and the wall
    thickness shall not be decreased below that permitted by this
    specification. The outside diameter at the point of grinding may
    be reduced by the amount so removed.
    10.5.1 Wall thickness measurements shall be made with a
    mechanical caliper or with a properly calibrated nondestructive
    testing device of appropriate accuracy. In case of dispute, the
    measurement determined by use of the mechanical caliper shall
    govern.
    10.6 Weld repair shall be permitted only subject to the
    approval of the purchaser and in accordance with Specification
    A 999/A 999M.
    10.7 The finished pipe shall be reasonably straight.
  11. General Requirements
    11.1 Material furnished to this specification shall conform to
    the applicable requirements of the current edition of Specification
    A 999/A 999M unless otherwise provided herein.
    A 333/A 333M – 04a
    3
    TABLE 3 Tensile Requirements
    Grade 1 Grade 3 Grade 4 Grade 6 Grade 7 Grade 8 Grade 9 Grade 10 Grade 11
    psi MPa psi MPa psi MPa psi MPa psi MPa psi MPa psi MPa psi MPa psi MPa
    Tensile strength, min
    Yield strength, min
    55 000
    30 000
    380
    205
    65 000
    35 000
    450
    240
    60 000
    35 000
    415
    240
    60 000
    35 000
    415
    240
    65 000
    35 000
    450
    240
    100 000
    75 000
    690
    515
    63 000
    46 000
    435
    315
    80 000
    65 000
    550
    450
    65 000
    35 000
    450
    240
    Longitudinal
    Transverse
    Longitudinal
    Transverse
    Longitudinal
    Transverse
    Longitudinal
    Transverse
    Longitudinal
    Transverse
    Longitudinal
    Transverse
    Longitudinal
    Transverse
    Longitudinal
    Transverse
    Longitudinal
    Elongation in 2 in. or 50
    mm, (or 4D), min, %:
    Basic minimum
    elongation for walls 5⁄16
    in. [8 mm] and over in
    thickness, strip tests,
    and for all small sizes
    tested in full section
    35 25 30 20 30 16.5 30 16.5 30 22 22 … 28 … 22 … 18A
    When standard round
    2-in. or 50-mm gage
    length or proportionally
    smaller size test
    specimen with the gage
    length equal to 4D (4
    times the diameter) is
    used
    28 20 22 14 22 12 22 12 22 14 16 … … … 16 … …
    For strip tests, a
    deduction for each 1⁄32
    in. [0.8 mm] decrease in
    wall thickness below 5⁄16
    in. [8 mm] from the
    basic minimum
    elongation of the
    following percentage
    1.75B 1.25B 1.50B 1.00B 1.50B 1.00B 1.50B 1.00B 1.50B 1.00B 1.25B … 1.50B … 1.25B … . . .
    Wall Thickness
    Elongation in 2 in. or 50 mm, min, %C
    Grade 1 Grade 3 Grade 4 Grade 6 Grade 7 Grade 8 Grade 9 Grade 10
    in. mm Longi- Trans- Longi- Trans- Longi- Trans- Longi- Trans- Longi- Trans- Longi- Trans- Longi- Trans- Longi- Transtudinal
    verse tudinal verse tudinal verse tudinal verse tudinal verse tudinal verse tudinal verse tudinal verse
    5⁄16 (0.312) 8 35 25 30 20 30 16 30 16 30 22 22 … 28 … 22 …
    9⁄32 (0.281) 7.2 33 24 28 19 28 15 28 15 28 21 21 … 26 … 21 …
    1⁄4 (0.250) 6.4 32 23 27 18 27 15 27 15 27 20 20 … 25 … 20 …
    7⁄32 (0.219) 5.6 30 … 26 … 26 … 26 … 26 … 18 … 24 … 18 …
    3⁄16 (0.188) 4.8 28 … 24 … 24 … 24 … 24 … 17 … 22 … 17 …
    5⁄32 (0.156) 4 26 … 22 … 22 … 22 … 22 … 16 … 20 … 16 …
    1⁄8 (0.125) 3.2 25 … 21 … 21 … 21 … 21 … 15 … 19 … 15 …
    3⁄32 (0.094) 2.4 23 … 20 … 20 … 20 … 20 … 13 … 18 … 13 …
    1⁄16 (0.062) 1.6 21 … 18 … 18 … 18 … 18 … 12 … 16 … 12 …
    A Elongation of Grade 11 is for all walls and small sizes tested in full section.
    B The following table gives the calculated minimum values.
    C Calculated elongation requirements shall be rounded to the nearest whole number.
    Note—The preceding table gives the computed minimum elongation values for each 1⁄32-in. [0.80-mm] decrease in wall thickness. Where the wall thickness lies between
    two values shown above, the minimum elongation value is determined by the following equation:
    Grade Direction of Test Equation
    1 Longitudinal E = 56t + 17.50 [E = 2.19t + 17.50]
    Transverse E = 40t + 12.50 [E = 1.56t + 12.50]
    3 Longitudinal E = 48t + 15.00 [E = 1.87t + 15.00]
    Transverse E = 32t + 10.00 [E = 1.25t + 10.00]
    4 Longitudinal E = 48t + 15.00 [E = 1.87t + 15.00]
    Transverse E = 32t + 6.50 [E = 1.25t+ 6.50]
    6 Longitudinal E = 48t + 15.00 [E = 1.87t + 15.00]
    Transverse E = 32t + 6.50 [E = 1.25t + 6.50]
    7 Longitudinal E = 48t + 15.00 [E = 1.87t + 15.00]
    Transverse E = 32t + 11.00 [E = 1.25t + 11.00]
    8 and 10 Longitudinal E = 40t + 9.50 [E = 1.56t + 9.50]
    9 Longitudinal E = 48t + 13.00 [E = 1.87t + 13.00]
    where:
    E = elongation in 2 in. or 50 mm, in %, and
    t = actual thickness of specimen, in. [mm].
    A 333/A 333M – 04a
    4
  12. Mechanical Testing
    12.1 Sampling—For mechanical testing, the term “lot” applies
    to all pipe of the same nominal size and wall thickness (or
    schedule) that is produced from the same heat of steel and
    subjected to the same finishing treatment in a continuous
    furnace. If the final heat treatment is in a batch-type furnace,
    the lot shall include only those pipes that are heat treated in the
    same furnace charge.
    12.2 Transverse or Longitudinal Tensile Test and Flattening
    Test—For material heat treated in a batch-type furnace, tests
    shall be made on 5 % of the pipe from each lot. If heat treated
    by the continuous process, tests shall be made on a sufficient
    number of pipe to constitute 5 % of the lot, but in no case less
    than 2 pipes.
    12.3 Hydrostatic Test—Each length of pipe shall be subjected
    to the hydrostatic test.
    12.4 Impact Test—One notched bar impact test, consisting
    of breaking three specimens, shall be made from each heat
    represented in a heat-treatment load on specimens taken from
    the finished pipe. This test shall represent only pipe from the
    same heat and the same heat-treatment load, the wall thicknesses
    of which do not exceed by more than 1⁄4 in. [6.3 mm] the
    wall thicknesses of the pipe from which the test specimens are
    taken. If heat treatment is performed in continuous or batchtype
    furnaces controlled within a 50°F [30°C] range and
    equipped with recording pyrometers so that complete records
    of heat treatment are available, then one test from each heat in
    a continuous run only shall be required instead of one test from
    each heat in each heat-treatment load.
    12.5 Impact Tests (Welded Pipe)—On welded pipe, additional
    impact tests of the same number as required in 12.3 or
    12.4 shall be made to test the weld.
    12.6 Specimens showing defects while being machined or
    prior to testing may be discarded and replacements shall be
    considered as original specimens.
    12.7 Results obtained from these tests shall be reported to
    the purchaser or his representative.
  13. Specimens for Impact Test
    13.1 Notched bar impact specimens shall be of the simple
    beam, Charpy-type, in accordance with Test Methods E 23,
    Type A with a V notch. Standard specimens 10 by 10 mm in
    cross section shall be used unless the material to be tested is of
    insufficient thickness, in which case the largest obtainable
    subsize specimens shall be used. Charpy specimens of width
    along the notch larger than 0.394 in. [10 mm] or smaller than
    0.099 in. [2.5 mm] are not provided for in this specification.
    13.2 Test specimens shall be obtained so that the longitudinal
    axis of the specimen is parallel to the longitudinal axis of
    the pipe while the axis of the notch shall be perpendicular to
    the surface. On wall thicknesses of 1 in. [25 mm] or less, the
    specimens shall be obtained with their axial plane located at the
    midpoint; on wall thicknesses over 1 in. [25 mm], the specimens
    shall be obtained with their axial plane located 1⁄2 in.
    [12.5 mm] from the outer surface.
    13.3 When testing welds the specimen shall be, whenever
    diameter and thickness permit, transverse to the longitudinal
    axis of the pipe with the notch of the specimen in the welded
    joint and perpendicular to the surface. When diameter and
    thickness do not permit obtaining transverse specimens, longitudinal
    specimens in accordance with 13.2 shall be obtained;
    the bottom of the notch shall be located at the weld joint.
  14. Impact Test
    14.1 Except when the size of the finished pipe is insufficient
    to permit obtaining subsize impact specimens, all material
    furnished to this specification and marked in accordance with
    Section 16 shall be tested for impact resistance at the minimum
    temperature for the respective grades as shown in Table 5.
    14.1.1 Special impact tests on individual lots of material
    may be made at other temperatures as agreed upon between the
    manufacturer and the purchaser.
    14.1.2 When subsize Charpy impact specimens are used and
    the width along the notch is less than 80 % of the actual wall
    thickness of the original material, the specified Charpy impact
    test temperature for Grades 1, 3, 4, 6, 7, 9, and 10 shall be
    lower than the minimum temperature shown in Table 5 for the
    respective grade. Under these circumstances the temperature
    reduction values shall be by an amount equal to the difference
    (as shown in Table 6) between the temperature reduction
    corresponding to the actual material thickness and the temperature
    reduction corresponding to the Charpy specimen width
    actually tested. Appendix X1 shows some examples of how the
    temperature reductions are determined.
    14.2 The notched bar impact test shall be made in accordance
    with the procedure for the simple beam, Charpy-type test
    of Test Methods E 23.
    14.3 Impact tests specified for temperatures lower than 70°F
    [20°C] should be made with the following precautions. The
    impact test specimens as well as the handling tongs shall be
    cooled a sufficient time in a suitable container so that both
    reach the desired temperature. The temperature shall be measured
    with thermocouples, thermometers, or any other suitable
    TABLE 4 Impact Requirements for Grades 1, 3, 4, 6, 7, 9, and 10
    Size of
    Specimen, mm
    Minimum Average Notched
    Bar Impact Value of
    Each Set of Three
    SpecimensA
    Minimum Notched Bar
    Impact Value of One
    Specimen Only of
    a SetA
    ft·lbf J ft·lbf J
    10 by 10 13 18 10 14
    10 by 7.5 10 14 8 11
    10 by 6.67 9 12 7 9
    10 by 5 7 9 5 7
    10 by 3.33 5 7 3 4
    10 by 2.5 4 5 3 4
    A Straight line interpolation for intermediate values is permitted.
    TABLE 5 Impact Temperature
    Grade
    Minimum Impact Test Temperature
    °F °C
    1 −50 −45
    3 −150 −100
    4 −150 −100
    6 −50 −45
    7 −100 −75
    8 −320 −195
    9 −100 −75
    10 −75 −60
    A 333/A 333M – 04a
    5
    devices and shall be controlled within 3°F [2°C]. The specimens
    shall be quickly transferred from the cooling device to
    the anvil of the Charpy impact testing machine and broken with
    a time lapse of not more than 5 s.
  15. Hydrostatic or Nondestructive Electric Test
    15.1 Each pipe shall be subjected to the nondestructive
    electric test or the hydrostatic test. The type of test to be used
    shall be at the option of the manufacturer, unless otherwise
    specified in the purchase order.
    15.2 The hydrostatic test shall be in accordance with Specification
    A 999/A 999M.
    15.3 Nondestructive Electric Test—Nondestructive electric
    tests shall be in accordance with Specification A 999/A 999M,
    with the following addition:
    15.3.1 If the test signals were produced by visual imperfections
    (listed in 15.3.2), the pipe may be accepted based on
    visual examination, provided the imperfection is less than
    0.004 in. (0.1 mm) or 12½ % of the specified wall thickness
    (whichever is greater).
    15.3.2 Visual Imperfections:
    15.3.2.1 Scratches,
    15.3.2.2 Surface roughness,
    15.3.2.3 Dings,
    15.3.2.4 Straightener marks,
    15.3.2.5 Cutting chips,
    15.3.2.6 Steel die stamps,
    15.3.2.7 Stop marks, or
    15.3.2.8 Pipe reducer ripple.
  16. Product Marking
    16.1 Except as modified in 16.1.1, in addition to the
    marking prescribed in Specification A 999/A 999M, the marking
    shall include whether hot finished, cold drawn, seamless or
    welded, the schedule number and the letters “LT” followed by
    the temperature at which the impact tests were made, except
    when a lower test temperature is required because of reduced
    specimen size, in which case, the higher impact test temperature
    applicable to a full-size specimen should be marked.
    16.1.1 When the size of the finished pipe is insufficient to
    obtain subsize impact specimens, the marking shall not include
    the letters “LT” followed by an indicated test temperature
    unless Supplementary Requirement S1 is specified.
    16.1.2 When the pipe is furnished in the quenched and
    tempered condition, the marking shall include the letters “QT,”
    and the heat treatment condition shall be reported to the
    purchaser or his representative.
  17. Keywords
    17.1 low; low temperature service; seamless steel pipe;
    stainless steel pipe; steel pipe; temperature service applications
    SUPPLEMENTARY REQUIREMENTS
    The following supplementary requirement shall apply only when specified by the purchaser in the
    contract or order.
    S1. Subsize Impact Specimens
    S1.1 When the size of the finished pipe is insufficient to
    permit obtaining subsize impact specimens, testing shall be a
    matter of agreement between the manufacturer and the
    purchaser.
    TABLE 6 Impact Temperature Reduction
    Specimen Width Along Notch or Actual
    Material Thickness
    Temperature Reduction,
    Degrees ColderA
    in. mm °F °C
    0.394 10 (standard size) 0 0
    0.354 9 0 0
    0.315 8 0 0
    0.295 7.5 (3⁄4 std. size) 5 3
    0.276 7 8 4
    0.262 6.67 (2⁄3 std. size) 10 5
    0.236 6 15 8
    0.197 5 (1⁄2 std. size) 20 11
    0.158 4 30 17
    0.131 3.33 (1⁄3 std. size) 35 19
    0.118 3 40 22
    0.099 2.5 (1⁄4 std. size) 50 28
    A Straight line interpolation for intermediate values is permitted.
    A 333/A 333M – 04a
    6
    APPENDIX
    (Nonmandatory Information)
    X1. DETERMINATION OF TEMPERATURE REDUCTIONS
    X1.1 Under the circumstances stated in 14.1.2, the impact
    test temperatures specified in Table 5 must be lowered. The
    following examples are offered to describe the application of
    the provisions of 14.1.2.
    X1.1.1 When subsize specimens are used (see 10.1) and the
    width along the notch of the subsize specimen in 80 % or
    greater of the actual wall thickness of the original material, the
    provisions of 14.1.2 do not apply.
    X1.1.1.1 For example, if the actual wall thickness of pipe
    was 0.200 in. [5.0 mm] and the width along the notch of the
    largest subsize specimen obtainable is 0.160 in. [4 mm] or
    greater, no reduction in test temperature is required.
    X1.1.2 When the width along the subsize specimen notch is
    less than 80 % of the actual wall thickness of the pipe, the
    required reduction in test temperature is computed by taking
    the difference between the temperature reduction values shown
    in Table 6 for the actual pipe thickness and the specimen width
    used.
    X1.1.2.1 For example, if the pipe were 0.262 in. [6.67 mm]
    thick and the width along the Charpy specimen notch was 3.33
    mm (1/3 standard size), the test temperature would have to be
    lowered by 25°F [14°C]. That is, the temperature reduction
    corresponding to the subsize specimen is 35°F [19°C]; the
    temperature reduction corresponding to the actual pipe thickness
    is 10°F [5°C]; the difference between these two values is
    the required reduction in test temperature.
    SUMMARY OF CHANGES
    Committee A01 has identified the location of selected changes to this specification since the last issue,
    A 333/A 333M – 04, that may impact the use of this specification. (Approved May 1, 2004)
    (1) Replaced all references to Note 4 in 9.1 with Note 3. (2) Revised Section 12 to incorporate Note 4 into the text.
    Committee A01 has identified the location of selected changes to this specification since the last issue, A 333/A 333M – 99,
    that may impact the use of this specification. (Approved March 1, 2004)
    (1) Replaced Specification A 530/A 530M with Specification
    A 999/A 999M in the Referenced Documents.
    (2) Replaced Specification A 530/A 530M with Specification
    A 999/A 999M in Sections 3, 11, 15, and 16.
    (3) Extensively revised Section 15.
    A 333/A 333M – 04a

Inspection & Approval Certificates : C/W Certificate (Calibration Works Certificate) EN-10204 3.1 / DIN-50049 3.1 / ISO-10474 3.1 Mill Test Certificate,
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